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41.
Nobutaka Shibata Daisuke Nagao Haruyuki Ishii Mikio Konno 《Colloid and polymer science》2013,291(1):137-142
Janus composite particles with a combination of organic and inorganic substances were synthesized by soap-free emulsion polymerization in which an amphoteric initiator of 2,2′-azobis[N-(2-carboxyethyl)-2-2-methylpropionamidine] (VA-057) was employed to introduce a polystyrene (PSt) lobe onto silica cores surface-modified with 3-methacryloxypropyltrimethoxy silane (MPTMS). Thermogravimetric analysis and X-ray photoelectron spectroscopy were used to characterize the surface-modified silica particles and showed that a small amount of MPTMS introduced onto the surface of silica particles could successfully prepare SiO2–PSt Janus particles. The oxide part of SiO2–PSt Janus particles obtained with the polymerization was further surface-modified with 3-aminopropyltriethoxysilane (APS) to introduce positively charged amino groups on the silica surface. The silica surface modified with APS was covered with gold by electroless deposition in which a gold precursor of auric chloride was reduced with ascorbic acid in the presence of polyvinylpyrrolidone. The electroless deposition of gold successfully produced Janus particles with a combination of gold and PSt surfaces. Furthermore, dissolution of the polymer component of the Au–PSt Janus particles in tetrahydrofuran led to another Janus type of particles with an inorganic combination of Au and SiO2. 相似文献
42.
Shimizu Y Shiokawa N Yamamoto N Kozuma M Kuga T Deng L Hagley EW 《Physical review letters》2002,89(23):233001
Propagation of a light pulse through a high-Q optical microcavity containing a few cold atoms (N<10) in its cavity mode is investigated experimentally. With less than ten cold rubidium atoms launched into an optical microcavity, up to 170 ns propagation lead time ("superluminal"), and 440 ns propagation delay time (subluminal) are observed. Comparison of the experimental data with numerical simulations as well as future experiments are discussed. 相似文献
43.
The proton magnetic resonance spectra of the three title carbanions have been observed in THF with potassium as a counter ion. The ortho-protons in the α-methylbenzyl carbanion are nonequivalent at room temperature. This shows that the α-carbon in this carbanion is in the near-sp2 configuration. The aromatic proton chemical shifts of the benzylpotassium obtained here are at higher shielding than those of benzyllithium reported previously by Sandel and Freedman. This seems to arise from the different ionic nature of the bonds between carbon and metal in the carbanions. 相似文献
44.
Mikio Kano 《Journal of Graph Theory》1985,9(1):129-146
Let a and b be integers such that 0 ? a ? b. Then a graph G is called an [a, b]-graph if a ? dG(x) ? b for every x ? V(G), and an [a, b]-factor of a graph is defined to be its spanning subgraph F such that a ? dF(x) ? b for every vertex x, where dG(x) and dF(x) denote the degrees of x in G and F, respectively. If the edges of a graph can be decomposed into [a.b]-factors then we say that the graph is [2a, 2a]-factorable. We prove the following two theorems: (i) a graph G is [2a, 2b)-factorable if and only if G is a [2am,2bm]-graph for some integer m, and (ii) every [8m + 2k, 10m + 2k]-graph is [1,2]-factorable. 相似文献
45.
In this paper we study the singular Fano compactifications of with small Gorenstein singularities and determine the structure of such a compactification in the case of the Fano index r 2.Mathematics Subject Classification (2000): 14J45 , 32J05 相似文献
46.
The squeezed vacuum resonant on the (87)Rb D1 line (probe light) was injected into an optically dense rubidium gas cell with a coherent light (control light). The output probe light maintained its quadrature squeezing within the transparency window caused by the electromagnetically induced transparency (EIT). The results reported here are the first realization of EIT in the full quantum regime. 相似文献
47.
Tsuboyama A Takiguchi T Okada S Osawa M Hoshino M Ueno K 《Dalton transactions (Cambridge, England : 2003)》2004,(8):1115-1116
The synthesis, structure, and photophysical properties of a new cyclometalated dinuclear iridium complex, (ppy)2Ir(mu-BPB)Ir(ppy)2 [ppy = 2-phenylpyridine, BPB = 1,4-bis(pyridin-2-yl)benzene], have been investigated. 相似文献
48.
The amount of information transmissible through a communications channel is determined by the noise characteristics of the channel and by the quantities of available transmission resources. In classical information theory, the amount of transmissible information can be increased twice at most when the transmission resource is doubled for fixed noise characteristics. In quantum information theory, however, the amount of information transmitted can increase even more than twice. We present a proof-of-principle demonstration of this superadditivity of classical capacity of a quantum channel by using the ternary symmetric states of a single photon, and by event selection from a weak coherent light source. We also show how the superadditive coding gain, even in a small code length, can boost the communication performance of the conventional coding technique. 相似文献
49.
Let X and Y be Banach spaces and ψ a continuous convex function on the unit interval [0,1] satisfying certain conditions. Let X⊕ψY be the direct sum of X and Y equipped with the associated norm with ψ. We show that X⊕ψY is uniformly convex if and only if X,Y are uniformly convex and ψ is strictly convex. As a corollary we obtain that the ?p,q-direct sum (not p=q=1 nor ∞), is uniformly convex if and only if X,Y are, where ?p,q is the Lorentz sequence space. These results extend the well-known fact for the ?p-sum . Some other examples are also presented. 相似文献
50.
Mikio Morita 《Tetrahedron》2008,64(8):1753-1758
The reaction of trimethylsilyldiazomethane with thiobenzoyl isocyanates, in situ generated from thiazole-4,5-diones, yielded diazoketones, which were converted into 2-azaazulenes by the intramolecular Buchner reaction. 相似文献